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The Semmelhack Lab

PUBLICATIONS

  1. Zhang Z, Ortega D, Rush A, Blankenship LR, Cheng ZJ, Moore RE, Tran MLN, Sandoval LG, Aboulhosn K, Watanabe S, Cortez KS, Perlman DH, Semmelhack MF, Miller Conrad LC. Antibiotic Adjuvant Activity Revealed in a Photoaffinity Approach to Determine the Molecular Target of Antipyocyanin Compounds. ACS Infect Dis. 2021 Mar 12;7(3):535-543. doi: 10.1021/acsinfecdis.0c00160. Epub 2021 Feb 15. PMID: 33587590; PMCID: PMC8325921.
  2. Boyaci H, Shah T, Hurley A, et al. Structure, Regulation, and Inhibition of the Quorum-Sensing Signal Integrator LuxO. Plos Biology. 2016 May;14(5):e1002464. DOI: 10.1371/journal.pbio.1002464. PMID: 27219477; PMCID: PMC4878744.
  3. Lu HD, Spiegel AC, Hurley A, et al. Modulating Vibrio cholerae quorum-sensing-controlled communication using autoinducer-loaded nanoparticles. Nano Letters. 2015 Apr;15(4):2235-2241. DOI: 10.1021/acs.nanolett.5b00151. PMID: 25651002; PMCID: PMC4390484.
  4. Miller LC, O’Loughlin CT, Zhang Z, et al. Development of potent inhibitors of pyocyanin production in Pseudomonas aeruginosa. Journal of Medicinal Chemistry. 2015 Feb;58(3):1298-1306. DOI: 10.1021/jm5015082. PMID: 25597392; PMCID: PMC4332565.
  5. Werner KM, Perez LJ, Ghosh R, Semmelhack MF, Bassler BL. Caenorhabditis elegans recognizes a bacterial quorum-sensing signal molecule through the AWCON neuron. The Journal of Biological Chemistry. 2014 Sep;289(38):26566-26573. DOI: 10.1074/jbc.m114.573832. PMID: 25092291; PMCID: PMC4176233.
  6. Perez LJ, Karagounis TK, Hurley A, Bassler BL, Semmelhack MF. Highly Potent, Chemically Stable Quorum Sensing Agonists for Vibrio Cholerae. Chemical Science. 2014 Jan;5(1):151-155. DOI: 10.1039/c3sc52572d. PMID: 24436778; PMCID: PMC3890260.
  7. Shi DD, Trigo FF, Semmelhack MF, Wang SS. Synthesis and biological evaluation of bis-CNB-GABA, a photoactivatable neurotransmitter with low receptor interference and chemical two-photon uncaging properties. Journal of the American Chemical Society. 2014 Feb;136(5):1976-1981. DOI: 10.1021/ja411082f. PMID: 24422544; PMCID: PMC3985807.
  8. O’Loughlin CT, Miller LC, Siryaporn A, et al. A quorum-sensing inhibitor blocks Pseudomonas aeruginosa virulence and biofilm formation. Proceedings of the National Academy of Sciences of the United States of America. 2013 Oct;110(44):17981-17986. DOI: 10.1073/pnas.1316981110. PMID: 24143808; PMCID: PMC3816427.
  9. Perez LJ, Ng WL, Marano P, Brook K, Bassler BL, Semmelhack MF. Role of the CAI-1 fatty acid tail in the Vibrio cholerae quorum sensing response. J Med Chem. 2012 Nov 26;55(22):9669-81. doi: 10.1021/jm300908t. Epub 2012 Nov 8. PMID: 23092313; PMCID: PMC3798069.
  10. Sambanthamoorthy K, Sloup RE, Parashar V, Smith JM, Kim EE, Semmelhack MF, Neiditch MB, Waters CM. Identification of small molecules that antagonize diguanylate cyclase enzymes to inhibit biofilm formation. Antimicrob Agents Chemother. 2012 Oct;56(10):5202-11. doi: 10.1128/AAC.01396-12. Epub 2012 Jul 30. PMID: 22850508; PMCID: PMC3457405.
  11. Ng WL, Perez L, Cong J, Semmelhack MF, Bassler BL. Broad spectrum pro-quorum-sensing molecules as inhibitors of virulence in vibrios. PLoS Pathog. 2012;8(6):e1002767. doi: 10.1371/journal.ppat.1002767. Epub 2012 Jun 28. PMID: 22761573; PMCID: PMC3386246.
  12. Bolitho ME, Perez LJ, Koch MJ, Ng WL, Bassler BL, Semmelhack MF. Small molecule probes of the receptor binding site in the Vibrio cholerae CAI-1 quorum sensing circuit. Bioorg Med Chem. 2011 Nov 15;19(22):6906-18. doi: 10.1016/j.bmc.2011.09.021. Epub 2011 Sep 17. PMID: 22001326; PMCID: PMC3673537.
  13. Sambanthamoorthy K, Gokhale AA, Lao W, Parashar V, Neiditch MB, Semmelhack MF, Lee I, Waters CM. Identification of a novel benzimidazole that inhibits bacterial biofilm formation in a broad-spectrum manner. Antimicrob Agents Chemother. 2011 Sep;55(9):4369-78. doi: 10.1128/AAC.00583-11. Epub 2011 Jun 27. PMID: 21709104; PMCID: PMC3165298.
  14. Marques JC, Lamosa P, Russell C, Ventura R, Maycock C, Semmelhack MF, Miller ST, Xavier KB. Processing the interspecies quorum-sensing signal autoinducer-2 (AI-2): characterization of phospho-(S)-4,5-dihydroxy-2,3-pentanedione isomerization by LsrG protein. J Biol Chem. 2011 May 20;286(20):18331-43. doi: 10.1074/jbc.M111.230227. Epub 2011 Mar 30. PMID: 21454635; PMCID: PMC3093905.
  15. Stanevich V, Jiang L, Satyshur KA, Li Y, Jeffrey PD, Li Z, Menden P, Semmelhack MF, Xing Y. The structural basis for tight control of PP2A methylation and function by LCMT-1. Mol Cell. 2011 Feb 4;41(3):331-42. doi: 10.1016/j.molcel.2010.12.030. PMID: 21292165; PMCID: PMC3060061.
  16. Wei Y, Perez LJ, Ng WL, Semmelhack MF, Bassler BL. Mechanism of Vibrio cholerae autoinducer-1 biosynthesis. ACS Chem Biol. 2011 Apr 15;6(4):356-65. doi: 10.1021/cb1003652. Epub 2011 Jan 13. PMID: 21197957; PMCID: PMC3077805.
  17. Ng WL, Perez LJ, Wei Y, Kraml C, Semmelhack MF, Bassler BL. Signal production and detection specificity in Vibrio CqsA/CqsS quorum-sensing systems. Mol Microbiol. 2011 Mar;79(6):1407-17. doi: 10.1111/j.1365-2958.2011.07548.x. Epub 2011 Jan 26. PMID: 21219472; PMCID: PMC3285556.
  18. Cowles CE, Li Y, Semmelhack MF, Cristea IM, Silhavy TJ. The free and bound forms of Lpp occupy distinct subcellular locations in Escherichia coli. Mol Microbiol. 2011 Mar;79(5):1168-81. doi: 10.1111/j.1365-2958.2011.07539.x. Epub 2011 Jan 24. PMID: 21219470; PMCID: PMC3090202.
  19. Ng WL, Wei Y, Perez LJ, Cong J, Long T, Koch M, Semmelhack MF, Wingreen NS, Bassler BL. Probing bacterial transmembrane histidine kinase receptor-ligand interactions with natural and synthetic molecules. Proc Natl Acad Sci U S A. 2010 Mar 23;107(12):5575-80. doi: 10.1073/pnas.1001392107. Epub 2010 Mar 8. PMID: 20212168; PMCID: PMC2851778.
  20. Kelly RC, Bolitho ME, Higgins DA, Lu W, Ng WL, Jeffrey PD, Rabinowitz JD, Semmelhack MF, Hughson FM, Bassler BL. The Vibrio cholerae quorum-sensing autoinducer CAI-1: analysis of the biosynthetic enzyme CqsA. Nat Chem Biol. 2009 Dec;5(12):891-5. doi: 10.1038/nchembio.237. Epub 2009 Oct 18. PMID: 19838203; PMCID: PMC2847429.
  21. Higgins DA, Pomianek ME, Kraml CM, Taylor RK, Semmelhack MF, Bassler BL. The major Vibrio cholerae autoinducer and its role in virulence factor production. Nature. 2007 Dec 6;450(7171):883-6. doi: 10.1038/nature06284. Epub 2007 Nov 14. PMID: 18004304.
  22. Rader BA, Campagna SR, Semmelhack MF, Bassler BL, Guillemin K. The quorum-sensing molecule autoinducer 2 regulates motility and flagellar morphogenesis in Helicobacter pylori. J Bacteriol. 2007 Sep;189(17):6109-17. doi: 10.1128/JB.00246-07. Epub 2007 Jun 22. PMID: 17586631; PMCID: PMC1951907.
  23. Pomianek ME, Semmelhack MF. Making bacteria behave: new agonists and antagonists of quorum sensing. ACS Chem Biol. 2007 May 22;2(5):293-5. doi: 10.1021/cb700098c. PMID: 17518429.
  24. Xavier KB, Miller ST, Lu W, Kim JH, Rabinowitz J, Pelczer I, Semmelhack MF, Bassler BL. Phosphorylation and processing of the quorum-sensing molecule autoinducer-2 in enteric bacteria. ACS Chem Biol. 2007 Feb 20;2(2):128-36. doi: 10.1021/cb600444h. Epub 2007 Mar 2. PMID: 17274596.
  25. Semmelhack MF, Hooley RJ, Kraml CM. Synthesis of plakortone B and analogs. Org Lett. 2006 Nov 9;8(23):5203-6. doi: 10.1021/ol0618656. PMID: 17078678.
  26. Rickard AH, Palmer RJ Jr, Blehert DS, Campagna SR, Semmelhack MF, Egland PG, Bassler BL, Kolenbrander PE. Autoinducer 2: a concentration-dependent signal for mutualistic bacterial biofilm growth. Mol Microbiol. 2006 Jun;60(6):1446-56. doi: 10.1111/j.1365-2958.2006.05202.x. PMID: 16796680.
  27. Semmelhack MF, Chlenov A, Ho DM. Accelerated arene ligand exchange in the (Arene)Cr(CO)2L series. J Am Chem Soc. 2005 Jun 1;127(21):7759-73. doi: 10.1021/ja042705x. PMID: 15913366.
  28. Semmelhack MF, Campagna SR, Federle MJ, Bassler BL. An expeditious synthesis of DPD and boron binding studies. Org Lett. 2005 Feb 17;7(4):569-72. doi: 10.1021/ol047695j. PMID: 15704896.
  29. Semmelhack MF, Sarpong R. Kinetic analysis of a reactive model enediyne.  Journal of Physical Organic Chemistry. 2004 July 30.
  30. Miller ST, Xavier KB, Campagna SR, Taga ME, Semmelhack MF, Bassler BL, Hughson FM. Salmonella typhimurium recognizes a chemically distinct form of the bacterial quorum-sensing signal AI-2. Mol Cell. 2004 Sep 10;15(5):677-87. doi: 10.1016/j.molcel.2004.07.020. PMID: 15350213.
  31. Semmelhack MF, Campagna SR, Hwa C, Federle MJ, Bassler BL. Boron binding with the quorum sensing signal AI-2 and analogues. Org Lett. 2004 Jul 22;6(15):2635-7. doi: 10.1021/ol048976u. PMID: 15255709.
  32. M.F Semmelhack, Richard J. Hooley, Palladium-catalyzed hydrostannylations of highly hindered acetylenes in hexane, Tetrahedron Letters, Volume 44, Issue 30, 2003, Pages 5737-5739, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(03)01327-3.
  33. Semmelhack MF, Wu L, Pascal RA Jr, Ho DM. Conformational control in activation of an enediyne. J Am Chem Soc. 2003 Sep 3;125(35):10496-7. doi: 10.1021/ja036763e. PMID: 12940713.
  34. M.F. Semmelhack, Mark Jaskowski, Richmond Sarpong, Douglas M. Ho, A simple synthesis and evaluation of the bicyclo[8.3.0] enediyne framework, Tetrahedron Letters, Volume 43, Issue 28, 2002, Pages 4947-4950, .SSN 0040-4039.
  35. M.F. Semmelhack, Richmond Sarpong, Jeffrey Bergman, Douglas M. Ho, Evaluation of alkene isomerization as a trigger for enediyne activation, Tetrahedron Letters, Volume 43, Issue 4, 2002, Pages 541-544, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)02139-6.
  36. Kipp RA, Case MA, Wist AD, Cresson CM, Carrell M, Griner E, Wiita A, Albiniak PA, Chai J, Shi Y, Semmelhack MF, McLendon GL. Molecular targeting of inhibitor of apoptosis proteins based on small molecule mimics of natural binding partners. Biochemistry. 2002 Jun 11;41(23):7344-9. doi: 10.1021/bi0121454. PMID: 12044166.
  37. M. F. Semmelhack, Andreas Lindenschmidt, and D. Ho, Preparation and Structure of Chiral Carbene Complexes of Manganese and Iron from Terminal Alkynes, Organometallics 2001 20 (19), 4114-4117, DOI: 10.1021/om010507y.
  38. Semmelhack MF, Chlenov A, Wu L, Ho D. Accelerated arene ligand exchange in areneCr(CO(3)) complexes. J Am Chem Soc. 2001 Aug 29;123(34):8438-9. doi: 10.1021/ja0161150. PMID: 11516310.
  39. Semmelhack MF, Jiang Y, Ho D. Synthesis of the amino sugar from C-1027. Org Lett. 2001 Jul 26;3(15):2403-6. doi: 10.1021/ol010119s. PMID: 11463327.
  40. M.F. Semmelhack, Ponnusamy Shanmugam, Development of an approach to the synthesis of the plakortones, Tetrahedron Letters, Volume 41, Issue 19, 2000, Pages 3567-3571, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)00464-0.
  41. Semmelhack MF, Hilt G, Selective functionalization of an insodurene-Cr(C0)3 complex, Synlett, 2000, 8, 1127-1128.
  42. M.F. Semmelhack, Gerhard Hilt, Jeremy H. Colley, SNAr reactions with fluoroarene-Cr(CO)2L complexes, where L is a potential linker ligand for solid phase synthesis, Tetrahedron Letters, Volume 39, Issue 42, 1998, Pages 7683-7686, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(98)01720-1.
  43. M.F. Semmelhack, Yansong Gu, Douglas M. Ho, A new framework for the cycloaromatization of enediynes under mild conditions, Tetrahedron Letters, Volume 38, Issue 32, 1997, Pages 5583-5586, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(97)01263-X.
  44. M.F Semmelhack, Hans-Günther Schmalz, Asymmetric induction in the nucleophile addition to η6-arene-tricarbonyl-chromium(0) complexes, Tetrahedron Letters, Volume 37, Issue 18, 1996, Pages 3089-3092, ISSN 0040-4039, https://doi.org/10.1016/0040-4039(96)00572-2.
  45. M. F. Semmelhack, Thomas Neu, and Francisco Foubelo, Arene 1,4-Diradical Formation from o-Dialkynylarenes, The Journal of Organic Chemistry 1994 59 (17), 5038-5047,
    DOI: 10.1021/jo00096a057.
  46. Robert E. Babine, Nan Zhang, Steven R. Schow, Zhangbao Xu, Randal A. Byrn, Richard C. Hastings, M.F. Semmelhack, Michael M. Wick, Suresh S. Kerwar, Design, structure activity and x-ray crystallographic studies of pseudosymmetrical nonpeptidyl HIV-1 protease inhibitors, Bioorganic & Medicinal Chemistry Letters, Volume 4, Issue 4, 1994, Pages 583-588, ISSN 0960-894X, https://doi.org/10.1016/S0960-894X(01)80159-1.
  47. Andrea Goti, Martin F. Semmelhack, Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0), Journal of Organometallic Chemistry, Volume 470, Issues 1–2, 1994, Pages C4-C7, ISSN 0022-328X, https://doi.org/10.1016/0022-328X(94)80181-9.
  48. M. F. Semmelhack, Suzzy Ho, D. Cohen, M. Steigerwald, M. C. Lee, G. Lee, Adam M. Gilbert, William D. Wulff, and Richard G. Ball, Metal-Catalyzed Cyclopropene Rearrangements for Benzannulation: Evaluation of an Anthraquinone Synthesis Pathway and Reevaluation of the Parallel Approach via Carbene-Chromium Complexes, Journal of the American Chemical Society 1994 116 (16), 7108-7122, DOI: 10.1021/ja00095a014.
  49. M. F. Semmelhack, W. R. Epa, A. W-H. Cheung, Y. Gu, C. Kim, N. Zhang, and W. Lew, Palladium-Promoted Synthesis of Ionophore Antibiotics. Strategy and Assembly of the Homochiral Tetrahydrofuran and Tetrahydropyran Portions of Tetronomycin, Journal of the American Chemical Society 1994 116 (16), 7455-7456, DOI: 10.1021/ja00095a078.
  50. M. F. Semmelhack, J. J. Gallagher, W.-d. Ding, G. Krishnamurthy, R. Babine, and G. A. Ellestad, The Effect on DNA Cleavage Potency of Tethering a Simple Cyclic Enediyne to a Netropsin Analog, The Journal of Organic Chemistry 1994 59 (16), 4357-4359, DOI: 10.1021/jo00095a002.
  51. M.F. Semmelhack, Paul Knochel, T. Singleton, A new approach to indole alkaloids via indole chromium complexes, Tetrahedron Letters, Volume 34, Issue 32, 1993, Pages 5051-5054, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)60673-1.
  52. M.F. Semmelhack, Hakjune Rhee, A synthesis of (−)-indolactam V, Tetrahedron Letters, Volume 34, Issue 9, 1993, Pages 1395-1398, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)60300-3.
  53. M.F. Semmelhack, W.R. Epa, Catalytic tandem oxy-palladation and vinylation, Tetrahedron Letters, Volume 34, Issue 45, 1993, Pages 7205-7208, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)79288-4.
  54. M.F. Semmelhack, James Gallagher, Cyclic conjugated enediynes via elimination of a thionocarbonate in a latent Z-hex-3-ene-1,5-diyne unit, Tetrahedron Letters, Volume 34, Issue 26, 1993, Pages 4121-4124, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)60507-5.
  55. M.F. Semmelhack, Hakjune Rhee, Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes, Tetrahedron Letters, Volume 34, Issue 9, 1993, Pages 1399-1402, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)60301-5.
  56. M. F. Semmelhack, J. J. Gallagher, T. Minami, and T. Date, The enol-keto trigger in initiating arene diradical formation in calicheamicin/esperamicin analogs, Journal of the American Chemical Society 1993 115 (24), 11618-11619, DOI: 10.1021/ja00077a079.
  57. M.F. Semmelhack, Thomas Neu, Francisco Foubelo, Arene 1,4-diradical formation from o-dialkynylarenes, Tetrahedron Letters, Volume 33, Issue 23, 1992, Pages 3277-3280, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)92066-5.
  58. Robert E. Babine, Nan Zhang, Alex R. Jurgens, Steven R. Schow, Parimal R. Desai, John C. James, M.F. Semmelhack, The use of HIV-1 protease structure in inhibitor design, Bioorganic & Medicinal Chemistry Letters, Volume 2, Issue 6, 1992, Pages 541-546, ISSN 0960-894X, https://doi.org/10.1016/S0960-894X(01)81194-X.
  59. M.F. Semmelhack, C.H. Cheng, A new method for the synthesis of iron azadiene and diene complexes. Reaction of (η2-RCHCHCOR′)Fe(CO)4 with aniline and ylide, Journal of Organometallic Chemistry, Volume 393, Issue 2, 1990, Pages 237-241, ISSN 0022-328X, https://doi.org/10.1016/0022-328X(90)80203-C.
  60. Craig A. Merlic, M.F. Semmelhack, An interesting chloride ion effect in the Heck reaction, Journal of Organometallic Chemistry, Volume 391, Issue 2, 1990, Pages C23-C27, ISSN 0022-328X, https://doi.org/10.1016/0022-328X(90)80183-Z.
  61. M.F. Semmelhack, Nakcheol Jeong, Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne, Tetrahedron Letters, Volume 31, Issue 5, 1990, Pages 605-608, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)94579-9.
  62. M.F. Semmelhack, J. Gallagher, D. Cohen, Bioreductive alkylation as a trigger for toxic effects of dynemicin, Tetrahedron Letters, Volume 31, Issue 11, 1990, Pages 1521-1522, ISSN 0040-4039, https://doi.org/10.1016/0040-4039(90)80005-7.
  63. Semmelhack, M. F., Kim, Chung, Zhang, N., Bodurow, C., Sanner, M., Dobler, W. and Meier, M. “Intramolecular alkoxy-carbonylation of hydroxy alkenes promoted by Pd(II)” Pure and Applied Chemistry, vol. 62, no. 10, 1990, pp. 2035-2040. https://doi.org/10.1351/pac199062102035.
  64. Semmelhack, M.F, Structure of dynemicin [2], Chemical and Engineering News, 1990.
  65. M.F. Semmelhack, Nakcheol Jeong, Gary R. Lee, The Effect of propargyl oxygen substituents in the carbene-chromium/alkyne cycloaddition, Tetrahedron Letters, Volume 31, Issue 5, 1990, Pages 609-610, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)94580-5.
  66. Diane Harris Boschelli, Dennis Powell, Veronica Sharky, M.F. Semmelhack, An improved synthesis of glycinamide ribonucleotide, Tetrahedron Letters, Volume 30, Issue 13, 1989,
    Pages 1599-1600, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)99530-3.
  67. M.F Semmelhack, Chung Ryeol Kim, Walter Dobler, Michael Meier, Controlled beta-hydride elimination during tetrahydropyran formation with Pd(II); diastereoselective formation of the tetrahydropyran ring of tetronomycin, Tetrahedron Letters, Volume 30, Issue 37, 1989, Pages 4925-4928, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)80544-X.
  68. M. F. Semmelhack and Nan Zhang, Stereoselective formation of tetrahydrofuran rings via intramolecular alkoxycarbonylation of hydroxyalkenes, The Journal of Organic Chemistry 1989 54 (19), 4483-4485, DOI: 10.1021/jo00280a003.
  69. M. F. Semmelhack and Jaiwook Park, Coupling of 1,3-dienes with carbene-iron complexes to give substituted (1,3-diene)Fe(CO)3 derivatives, Journal of the American Chemical Society 1987 109 (3), 935-936, DOI: 10.1021/ja00237a069.
  70. M.F. Semmelhack, E.J. Fewkes, De-protonation of (η4-isoprene)Fe(CO)3; an isoprene anion equivalent, Tetrahedron Letters, Volume 28, Issue 14, 1987, Pages 1497-1500, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)81025-X.
  71. M. F. Semmelhack, Suzzy Ho, Michael Steigerwald, and M. C. Lee, Metal carbonyl-promoted rearrangement of cyclopropenes to naphthols, Journal of the American Chemical Society 1987 109 (14), 4397-4399, DOI: 10.1021/ja00248a047.
  72. M. F. Semmelhack and G. R. Lee, Preparation of acylpentacarbonylchromate salts and alkoxycarbene pentacarbonyl complexes of chromium employing the pentacarbonylchromate dianion ([Cr(CO)5]2-), Organometallics 1987 6 (9), 1839-1844, DOI: 10.1021/om00152a002.
  73. M.F. Semmelhack, Christopher R. Schmid, David A. Cortés, Mechanism of the oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium cation, Tetrahedron Letters,
    Volume 27, Issue 10, 1986, Pages 1119-1122, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)84193-3.
  74. M. F. Semmelhack and Jaiwook Park, Reaction of (aminocarbene)iron complexes with alkynes. A synthesis of 5-aminofurans, Organometallics 1986 5 (12), 2550-2552 DOI: 10.1021/om00143a025.
  75. M. F. Semmelhack, J. J. Harrison, D. C. Young, A. Gutierrez, Shahin Rafii, and Jon Clardy, [3.3]Metacyclophane: a novel synthesis and a study of the structure through x-ray diffraction, molecular mechanics, and solution NMR analysis, Journal of the American Chemical Society 1985 107 (25), 7508-7514, DOI: 10.1021/ja00311a047.
  76. M. F. Semmelhack, L. Keller, T. Sato, E. J. Spiess, and W. Wulff, Conjugate addition of acylate-nickel complexes to quinone monoketals: formal synthesis of the naphthoquinone antibiotics nanaomycin A and deoxyfrenolicin, The Journal of Organic Chemistry 1985 50 (26), 5566-5574 DOI: 10.1021/jo00350a027.
  77. M.F. Semmelhack, Preface, Tetrahedron, Volume 41, Issue 24,  1985, Pages xiii-xiv,  ISSN 0040-4020, https://doi.org/10.1016/S0040-4020(01)91410-3.
  78. M. F. Semmelhack, Yohini Appapillai, and Tadahisa Sato, Stereospecific synthesis of the bicyclo[2.2.2] portion of granaticin; synthesis of sarubicin A, Journal of the American Chemical Society 1985 107 (15), 4577-4579, DOI: 10.1021/ja00301a050
  79. M.F. Semmelhack, Joseph J. Bozell, Leonard Keller, Tadahisa Sato, E.J. Spiess, W. Wulff, A. Zask, Synthesis of naphthoquinone antibiotics by intramolecular alkyne cycloaddition to carbene-chromium complexes, Tetrahedron, Volume 41, Issue 24, 1985, Pages 5803-5812, ISSN 0040-4020, https://doi.org/10.1016/S0040-4020(01)91420-6.
  80. Martin F. Semmelhack and Hanh T. M. Le, Transient ferracyclobutanes during protonation of .eta.3-homoallyliron(0) complexes, Journal of the American Chemical Society 1985 107 (5), 1455-1457 DOI: 10.1021/ja00291a082
  81. M. Semmelhack and Christina Bodurow, Additions and Corrections – Intramolecular Alkoxypalladation/ Carbonylation of Alkenes. Journal of the American Chemical Society 1984 106 (18), 5388-5388 DOI: 10.1021/ja00330a606
  82. M. Semmelhack and Hanh Le, Additions and Corrections – Regioselectivity and Rearrangement upon Addition of Nucleophiles to (Diene)iron Complexes, Journal of the American Chemical Society 1984 106 (18), 5388-5389 DOI: 10.1021/ja00330a607
  83. M.F. Semmelhack, Christina Bodurow, Mary Baum, Direct synthesis of pyran-lactones related to naphthoquinoneantibiotics,Tetrahedron Letters, Volume 25, Issue 30, 1984, Pages 3171-3174, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)91000-7.
  84. Semmelhack, M.F.; Bodurow, C. Erratum: Intramolecular alkoxypalladation/carbonylation of alkenes (Journal of the American Chemical Society (1984) 106, (1496-1498)
  85. Martin F. Semmelhack and Christina Bodurow, Intramolecular alkoxypalladation/carbonylation of alkenes , Journal of the American Chemical Society 1984 106 (5), 1496-1498 DOI: 10.1021/ja00317a059
  86. M.F. Semmelhack, James W. Herndon, New iron complexes from nucleophile addition/carbonylation of η4-(1,3-diene)tricarbonyliron(0) complexes, Journal of Organometallic Chemistry, Volume 265, Issue 2, 1984, Pages c15-c18,
    ISSN 0022-328X, https://doi.org/10.1016/0022-328X(84)80077-7.
  87. M. F. Semmelhack, Christopher R. Schmid, David A. Cortes, and Chuen S. Chou, Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion, Journal of the American Chemical Society 1984 106 (11), 3374-3376 DOI: 10.1021/ja00323a064
  88. M. F. Semmelhack, Rui Tamura, Wayne Schnatter, and James Springer, The reaction of alkynes with (ethoxyalkylidene)tetracarbonyliron(0) complexes Journal of the American Chemical Society 1984 106 (18), 5363-5364
    DOI: 10.1021/ja00330a061
  89. M. F. Semmelhack and Hanh T. M. Le, Regioselectivity and rearrangement upon addition of nucleophiles to dieneiron complexes, Journal of the American Chemical Society 1984 106 (9), 2715-2717 DOI: 10.1021/ja00321a049
  90. M.F. Semmelhack, Chapter 8 – The Synthesis of Fomannosin and Illudol, Editor(s): Thomas Lindberg, Strategies and Tactics in Organic Synthesis, Academic Press, Volume 1, 1984, Pages 201-222, ISSN 1874-6004, ISBN 9780124502802,
  91. M. F. Semmelhack and Rui Tamura, Control over site of alkylation in iron acylate complexes: general preparation and reactions of alkylidene-iron tetracarbonyl complexes Journal of the American Chemical Society 1983 105 (12), 4099-4100
    DOI: 10.1021/ja00350a063
  92. M. F. Semmelhack and Rui Tamura, Coupling of alkenes with Fischer-type alkylidene complexes of iron Journal of the American Chemical Society 1983 105 (22), 6750-6752 DOI: 10.1021/ja00360a053
  93. M. F. Semmelhack, James W. Herndon, and John K. Liu, Cyclopentanones from nucleophilic addition/carbonylation to (.eta.4-diene)Fe(CO)3 complexes Organometallics 1983 2 (12), 1885-1888 DOI: 10.1021/om50006a035
  94. M. F. Semmelhack, Chuen S. Chou, and David A. Cortes, Nitroxyl-mediated electrooxidation of alcohols to aldehydes and ketones Journal of the American Chemical Society 1983 105 (13), 4492-4494 DOI: 10.1021/ja00351a070
  95. M. F. Semmelhack and Christopher R. Schmid, Nitroxyl-mediated electro-oxidation of amines to nitriles and carbonyl compoundsJournal of the American Chemical Society 1983 105 (22), 6732-6734 DOI: 10.1021/ja00360a042
  96. M. F. Semmelhack, James W. Herndon, and James P. Springer, Nucleophile addition/carbonylation with .eta.4-dienetricarbonyliron(0) complexes Journal of the American Chemical Society 1983 105 (8), 2497-2499
    DOI: 10.1021/ja00346a078
  97. M. F. Semmelhack, J. L. Garcia, D. Cortes, R. Farina, R. Hong, and B. K. Carpenter, Nucleophilic addition to (.eta.6(alkylbenzene)Cr(CO)3) complexes. Dependence of regioselectivity on the size of the alkyl group and the reactivity of the nucleophile Organometallics 1983 2 (3), 467-469 DOI: 10.1021/om00075a025
  98. M. F. Semmelhack and James W. Herndon, Scope of anion addition to (.eta.4-1,3-cyclohexadiene)tricarbonyliron(0) Organometallics 1983 2 (3), 363-372 DOI: 10.1021/om00075a002
  99. M. F. Semmelhack and A. Zask, Synthesis of racemic frenolicin via organochromium and organopalladium intermediates Journal of the American Chemical Society 1983 105 (7), 2034-2043 DOI: 10.1021/ja00345a061
  100. M.F. Semmelhack, Walter Seufert, L. Keller, Arene-metal complexes: Preparation and reactions of h6-arene-Cr(CO)2(diphos) and analogs, Journal of Organometallic Chemistry, Volume 226, Issue 2, 1982, Pages 183-190,
    ISSN 0022-328X, https://doi.org/10.1016/S0022-328X(00)87434-3.
  101. M.F. Semmelhack, Joseph J. Bozell, Naphthoquinones from alkynes and chromium-carbene complexes-control of regioselectivity through intramolecular reaction,Tetrahedron Letters, Volume 23, Issue 29, 1982, Pages 2931-2934,
    ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(00)87497-3.
  102. M.F Semmelhack, W Wulff, J.L Garcia, New substitution reactions on indole promoted by the Cr(CO)3 unit, Journal of Organometallic Chemistry, Volume 240, Issue 1, 1982, Pages C5-C10, ISSN 0022-328X, https://doi.org/10.1016/S0022-328X(00)93987-1.
  103. Martin F. Semmelhack, Christina Ullenius, On the stability and decomposition of η6-(2-lithiochlorobenzene)tricarbonylchromium(0), Journal of Organometallic Chemistry, Volume 235, Issue 1, 1982, Pages C10-C12, ISSN 0022-328X, https://doi.org/10.1016/S0022-328X(00)85731-9.
  104. W. Roy Jackson, Ian D. Rae, Margaret G. Wong, Martin F. Semmelhack and John N. Garcia, Stereoelectronic control of the regioselectivity of both electrophilic and nucleophilic substitution of η6-(1,1-dimethylindane)tricarbonyl-chromium(0) J. Chem. Soc., Chem. Commun., 1982, 1359-1360
  105. M. F. Semmelhack and Raj N. Misra, Stereoselective ketone reductions: reduction of 4-tert-butylcyclohexanone by alkylsilanes in the presence of rhodium(I) and ruthenium(II) catalysts, The Journal of Organic Chemistry 1982 47 (12), 2469-2471 DOI: 10.1021/jo00133a045
  106. M. F. Semmelhack, Joseph J. Bozell, Tadahisa Sato, W. Wulff, E. Spiess, and A. Zask, The synthesis of nanaomycin A and deoxyfrenolicin by alkyne cycloaddition to chromium-carbene complexes, Journal of the American Chemical Society 1982 104 (21), 5850-5852 DOI: 10.1021/ja00385a079
  107. M. F. Semmelhack, Leonard Keller, Tadahisa Sato, and E. Spiess, Synthesis of naphthoquinone antibiotics: conjugate addition/electrophile trapping with acylnickel carbonylate anions, The Journal of Organic Chemistry 1982 47 (22), 4382-4384 DOI: 10.1021/jo00143a055
  108. M. F. Semmelhack, Shuji Tomoda, Hiroto Nagaoka, Susan D. Boettger, and Kenneth M. Hurst, Synthesis of racemic fomannosin and illudol using a biosynthetically patterned common intermediate, Journal of the American Chemical Society 1982 104 (3), 747-759 DOI: 10.1021/ja00367a018
  109. M.F. Semmelhack, G.R. Clark, J.L. Garcia, J.J. Harrison, Y. Thebtaranonth, W. Wulff, A. Yamashita, Addition of carbon nucleophiles to arene-chromium complexes, Tetrahedron,
    Volume 37, Issue 23, 1981, Pages 3957-3965, ISSN 0040-4020, https://doi.org/10.1016/S0040-4020(01)93270-3.
  110. M. F. Semmelhack and Steven J. Brickner, Intramolecular carbonylation of vinyl halides to form methylene lactones, The Journal of Organic Chemistry 1981 46 (8), 1723-1726
    DOI: 10.1021/jo00321a040
  111. M. F. Semmelhack and Steven J. Brickner, Nickel-promoted cyclization/carbonylation in the preparation of .alpha.-methylene-.gamma.lactones. Stereospecific synthesis of (.+-.)-frullanolide, Journal of the American Chemical Society 1981 103 (13), 3945-3947 DOI: 10.1021/ja00403a065
  112. M. F. Semmelhack, Paul Helquist, L. D. Jones, Leonard Keller, L. Mendelson, Laurine Speltz Ryono, Janice Gorzynski Smith, and R. D. Stauffer, Reaction of aryl and vinyl halides with zerovalent nickel – preparative aspects and the synthesis of alnusone, Journal of the American Chemical Society 1981 103 (21), 6460-6471 DOI: 10.1021/ja00411a034
  113. M. F. Semmelhack and Shuji Tomoda, Synthesis of (.+-.)-fomannosin, Journal of the American Chemical Society 1981 103 (9), 2427-2428 DOI: 10.1021/ja00399a057
  114. M. F. Semmelhack and A. Yamashita, Arene-metal complexes in organic synthesis: synthesis of acorenone and acorenone B, Journal of the American Chemical Society 1980 102 (18), 5924-5926 DOI: 10.1021/ja00538a046
  115. M. F. Semmelhack, Walter Seufert, and Leonard Keller, Arene-metal complexes in organic synthesis: addition to styrene-type ligands, Journal of the American Chemical Society 1980 102 (21), 6584-6586 DOI: 10.1021/ja00541a048
  116. M. F. Semmelhack and Thomas Bargar, Photostimulated nucleophilic aromatic substitution for halides with carbon nucleophiles. Preparative and mechanistic aspects,
    Journal of the American Chemical Society 1980 102 (26), 7765-7774 DOI: 10.1021/ja00546a021
  117. M. F. Semmelhack, Shuji Tomoda, and K. M. Hurst, Synthesis of (.+-.)-illudol, Journal of the American Chemical Society 1980 102 (25), 7567-7568 DOI: 10.1021/ja00545a031
  118. M. F. Semmelhack, J. J. Harrison, and Y. Thebtaranonth, Formation of 3-substituted cyclohexenones by nucleophilic addition to anisole-chromium complexes,The Journal of Organic Chemistry 197944 (18), 3275-3277 DOI: 10.1021/jo01332a043
  119. M. F. Semmelhack, G. R. Clark, R. Farina, and M. Saeman, Substituent effects in addition of carbanions to arenechromium tricarbonyl complexes: correlation with arene LUMO, Journal of the American Chemical Society 1979 101 (1), 217-218, DOI: 10.1021/ja00495a036
  120. M. F. Semmelhack, H. T. Hall Jr., R. Farina, M. Yoshifuji, G. Clark, T. Bargar, K. Hirotsu, and J. Clardy, .eta.5-Cyclohexadienyltricarbonylchromium(0) complexes from addition of carbon nucleophiles to .eta.6-benzenetricarbonylchromium(0). Formation, chemical and spectroscopic features, and x-ray diffraction analysis, Journal of the American Chemical Society 1979 101 (13), 3535-3544 DOI: 10.1021/ja00507a019
  121. M. F. Semmelhack, J. C. Tomesch, M. Czarny, and S. Boettger, Preparation of 2-(alkylthiomethyl)acrylates, The Journal of Organic Chemistry 1978 43 (6), 1259-1262 DOI: 10.1021/jo00400a057
  122. M. F. Semmelhack, H. N. Weller, and Jon Clardy, Rapid vinyl shifts in spiro[4.4]polyenes: verification of the rate-determining step and the identity of the migrating group, The Journal of Organic Chemistry 1978 43 (19), 3791-3792 DOI: 10.1021/jo00413a042
  123. M. F. Semmelhack, A. Yamashita, J. C. Tomesch, and K. Hirotsu, Total synthesis of confertin via metal-promoted cyclization-lactonization, Journal of the American Chemical Society 1978 100 (17), 5565-5567 DOI: 10.1021/ja00485a052
  124. Semmelhack, M.F. (1977), ARENE-METAL COMPLEXES IN ORGANIC SYNTHESIS. Annals of the New York Academy of Sciences, 295: 36-51. https://doi.org/10.1111/j.1749-6632.1977.tb41821.x
  125. M. F. Semmelhack and Thomas M. Bargar, Cyclizations of enolates onto aromatic rings via the photo-SRN1 reaction. Preparative and mechanistic aspects, The Journal of Organic Chemistry 1977 42 (8), 1481-1482 DOI: 10.1021/jo00428a056
  126. M. F. Semmelhack and J. C. Tomesch, Grob-type fragmentation of five- and six-membered rings promoted by cuprous ion, The Journal of Organic Chemistry 1977 42 (15), 2657-2658 DOI: 10.1021/jo00435a039
  127. M. F. Semmelhack and G. Clark, Meta-substituted aromatics by carbanion attack on .pi.-anisole and .pi.-toluenechromium tricarbonyl, Journal of the American Chemical Society 1977 99 (5), 1675-1676 DOI: 10.1021/ja00447a081
  128. M. F. Semmelhack, R. D. Stauffer, and A. Yamashita, Reductions of conjugated carbonyl compounds with copper hydride – preparative and mechanistic aspects, The Journal of Organic Chemistry 1977 42 (19), 3180-3188 DOI: 10.1021/jo00439a015
  129. M. F. Semmelhack, H. N. Weller, and J. S. Foos, Thermal rearrangements of spiro[4.4]nonapolyenes. Unusually rapid 1,5-vinyl migration, Journal of the American Chemical Society 1977 99 (1), 292-294 DOI: 10.1021/ja00443a074
  130. M. F. Semmelhack and E. S. C. Wu, Synthetic methods for sesquiterpene .alpha.-methylene-.gamma.-lactones, Journal of the American Chemical Society 1976 98 (11), 3384-3386 DOI: 10.1021/ja00427a062
  131. M. F. Semmelhack, H. T. Hall Jr., and M. Yoshifuji,.eta.5-Cyclohexadienyltricarbonylchromium(0) intermediates in the reaction of carbanions with .eta.6-arenetricarbonylchromium(0), Journal of the American Chemical Society 1976 98 (20), 6387-6389 DOI: 10.1021/ja00436a056
  132. M. F. Semmelhack and Lauri S. Ryono, Nickel-promoted synthesis of cyclic biphenyls. Total synthesis of alnusone dimethyl ether, Journal of the American Chemical Society 1975 97 (13), 3873-3875 DOI: 10.1021/ja00846a084
  133. M. F. Semmelhack, H. T. Hall, M. Yoshifuji, and G. Clark, Reactions of carbonions with .pi.-benzenechromium tricarbonyl. Nucleophilic aromatic substitution for hydride, Journal of the American Chemical Society 1975 97 (5), 1247-1248 DOI: 10.1021/ja00838a051
  134. Martin F. Semmelhack and R. D. Stauffer, Reductions with copper hydride. New preparative and mechanistic aspects, The Journal of Organic Chemistry 1975 40 (24), 3619-3621
    DOI: 10.1021/jo00912a040
  135. Altman, L. J., Semmelhack, M. F., Hornby, R. B., & Vederas, J. C. (1975). SYNTHESIS OF DIMETHYL 1,2-DIHYDROPYRIDAZINE-1,2-DICARBOXYLATE. Organic Preparations and Procedures International, 7(1), 35–37. https://doi.org/10.1080/00304947509356812
  136. Steven M. Weinreb and Martin F. Semmelhack, Synthesis of the Cephalotaxus alkaloids, Accounts of Chemical Research 1975 8 (5), 158-164 DOI: 10.1021/ar50089a003
  137. M. F. Semmelhack, B. P. Chong, R. D. Stauffer, T. D. Rogerson, A. Chong, and Lawrence D. Jones, Total synthesis of the Cephalotaxus alkaloids. Problem in nucleophilic aromatic substitution, Journal of the American Chemical Society 1975 97 (9), 2507-2516 DOI: 10.1021/ja00842a031
  138. C. Batich, E. Heilbronner, Erika Rommel, M. F. Semmelhack, and J. S. Foos, Equivalence of the energy gaps .DELTA.I(1,2) and .DELTA.E(1,2) between corresponding bands in the photoelectron (I) and electronic absorption (E) spectra of spiro[4.4]nonatetraene. Amusing consequence of spiroconjugation, Journal of the American Chemical Society 1974 96 (25), 7662-7668 DOI: 10.1021/ja00832a011
  139. M. F. Semmelhack and H. T. Hall, Intermediates in the reaction of carbanions with .pi.-(chlorobenzene)chromium tricarbonyl, Journal of the American Chemical Society 1974 96 (22), 7092-7094 DOI: 10.1021/ja00829a044
  140. M. F. Semmelhack and H. T. Hall, Phenylation of carbanions by .pi.-(chlorobenzene)chromium tricarbonyl, Journal of the American Chemical Society 1974 96 (22), 7091-7092
    DOI: 10.1021/ja00829a043
  141. Batich, C., Heilbronner, E. and Semmelhack, M.F. (1973), Bemerkung zur Gleichheit der Aufspaltungen ΔI (zwischen den ersten beiden π-Ionisationspotentialen) und ΔE (zwischen den entsprechenden π* ← π Übergangsenergien) des Spiro[4,4]nonatetraens. Vorläufige Mitteilung. HCA, 56: 2110-2112. https://doi.org/10.1002/hlca.19730560639
  142. M.F. Semmelhack, Lauri Ryono, Carbon-carbon bond formation via transition metals: addition-elimination of aryl and alkenyl halides to methyltris (triphenylphosphine)rhodium (I), Tetrahedron Letters, Volume 14, Issue 31, 1973, Pages 2967-2970, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)96294-X.
  143. M.F. Semmelhack, R.D. Stauffer, T.D. Rogerson, Nucleophilic aromatic substitution via a new nickel-catalyzed process and via the SRN1 reaction. Improved synthesis of cephalotaxinone, Tetrahedron Letters, Volume 14, Issue 45, 1973, Pages 4519-4522, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)87265-8.
  144. M. F. Semmelhack, J. S. Foos, and S. Katz, Spiro[4.4]nonatetraene and spiro[4.4]nona-1,3,7-triene. Synthesis and properties. Effects of spiroconjugation, Journal of the American Chemical Society 1973 95 (22), 7325-7336 DOI: 10.1021/ja00803a021
  145. M. F. Semmelhack, R. J. DeFranco, Z. Margolin, and J. Stock, Spiroaromaticity in spiro[2.3]hexadienyl anions. Kinetic acidities in highly basic media, Journal of the American Chemical Society 1973 95 (2), 426-432 DOI: 10.1021/ja00783a019
  146. M.F. Semmelhack, R.D. Stauffer, Synthesis with zerovalent metals: conversion of thionocarbonates to alkenes with bis(1,5-cyclooctadiene)nickel(o)., Tetrahedron Letters, Volume 14, Issue 29, 1973, Pages 2667-2670, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)96108-8.
  147. M. F. Semmelhack, R. J. De Franco, Z. Margolin, and J. Stock, Kinetic acidity as a probe for spiroaromaticity in a spiro[2.3]hexadiene, Journal of the American Chemical Society 1972 94 (6), 2115-2116 DOI: 10.1021/ja00761a055
  148. M.F. Semmelhack, R.J. DeFranco, J. Stock, Selective introduction of hydrogen isotopes by electrolytic reduction of the carbon-halogen bond, Tetrahedron Letters, Volume 13, Issue 14, 1972, Pages 1371-1374, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)84630-X.
  149. M. F. Semmelhack and G. E. Heinsohn, Selective removal of protecting groups using controlled potential electrolysis, Journal of the American Chemical Society 1972 94 (14), 5139-5140 DOI: 10.1021/ja00769a087
  150. M. F. Semmelhack, J. S. Foos, and S. Katz, Spiro[4,4]nonatetraene and spiro[4,4]nona-1,3,7-triene, Journal of the American Chemical Society 1972 94 (24), 8637-8638
    DOI: 10.1021/ja00779a088
  151. M. F. Semmelhack and R. J. DeFranco, Synthesis and thermal rearrangements of spiro[2.3]hexadiene and spiro[2.3]hex-4-ene derivatives, Journal of the American Chemical Society 1972 94 (25), 8838-8847 DOI: 10.1021/ja00780a032
  152. M. F. Semmelhack, P. M. Helquist, and J. D. Gorzynski, Synthesis with zerovalent nickel. Coupling of alkenyl halides with bis(1,5-cyclooctadiene)nickel(0), Journal of the American Chemical Society 1972 94 (26), 9234-9236 DOI: 10.1021/ja00781a048
  153. M. F. Semmelhack and R. J. De Franco, Thermal rearrangements of spiro[2.3]hex-4-enes and spiro[2.3]hexadienes, Journal of the American Chemical Society 1972 94 (6), 2116-2118 DOI: 10.1021/ja00761a056
  154. M. F. Semmelhack, B. P. Chong, and L. D. Jones, Total synthesis of Cephalotaxus alkaloids, Journal of the American Chemical Society 1972 94 (24), 8629-8630DOI: 10.1021/ja00779a082
  155. M. F. Semmelhack, P. M. Helquist, and L. D. Jones, Synthesis with zerovalent nickel. Coupling of aryl halides with bis(1,5-cyclooctadiene)nickel(0), Journal of the American Chemical Society 1971 93 (22), 5908-5910 DOI: 10.1021/ja00751a062
  156. M.F. Semmelhack, R.J. DeFranco, The synthesis of spiro[2,3]hexenes and a spiro[2,3]hexadiene, Tetrahedron Letters, Volume 12, Issue 16, 1971, Pages 1061-1064, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)96625-0.
  157. M.F. Semmelhack, B.F. Gilman, Thiazepine photochemistry. Ready 1,3-hydrogen shifts from a side-chain amide, J. Chem. Soc. D, 1971, 988-989
  158. M.F. Semmelhack, Steve Kunkes, Carol S. Lee, Thiazepine photochemistry. The photoaddition of methanol involving participation by sulphur, J. Chem. Soc. D, 1971, 698-699
  159. William S. Johnson, Martin F. Semmelhack, M. U. S. Sultanbawa, and Lester A. Dolak, A new approach to steroid total synthesis. A nonenzymic biogenetic-like olefinic cyclization involving the stereospecific formation of five asymmetric centers, Journal of the American Chemical Society 1968 90 (11), 2994-2996 DOI: 10.1021/ja01013a066
  160. E. J. Corey, L. S. Hegedus, and M. F. Semmelhack, Interconversion of lower valence states of .pi.-allylnickel complexes. A new synthesis of .pi.-allylnickel derivatives, Journal of the American Chemical Society 1968 90 (9), 2417-2418 DOI: 10.1021/ja01011a036
  161. L. J. Altman, M. F. Semmelhack, R. B. Hornby and J. C. Vederas, Photochemical isomerisation of dimethyl 1,2-dihydropyridazine-1,2-dicarboxylate, Chem. Commun. (London), 1968, 686-687
  162. E. J. Corey, M. F. Semmelhack, and L. S. Hegedus, The course of allylic coupling reactions involving allylnickel complexes, Journal of the American Chemical Society 1968 90 (9), 2416-2417 DOI: 10.1021/ja01011a035
  163. Elias J. Corey and Martin F. Semmelhack, Organonickel compounds as reagents for selective carbon-carbon bond formation between unlike groups, Journal of the American Chemical Society 1967 89 (11), 2755-2757 DOI: 10.1021/ja00987a056
  164. E.J. Corey, Martin F. Semmelhack, Coupling and cyclization of dihalides using nickel carbonyl; a one-step synthesis of 1,4,7-thimethylenecyclononane from 1,1-bischloromethylethylene, Tetrahedron Letters, Volume 7, Issue 50, 1966, Pages 6237-6240, ISSN 0040-4039, https://doi.org/10.1016/S0040-4039(01)84136-8.
  165. Howard E. Zimmerman, Robert G. Lewis, John J. McCullough, Albert Padwa, Stuart W. Staley, and Martin Semmelhack, Mechanistic and Exploratory Photochemistry. XV.1 The Relation of Cyclohexenone to Cyclohexadienone Rearrangements, Journal of the American Chemical Society 1966 88 (9), 1965-1973 DOI: 10.1021/ja00961a021
  166. Howard E. Zimmerman, Robert G. Lewis, John J. McCullough, Albert Padwa, Stuart Staley, and Martin Semmelhack, The Relation of Cyclohexenone to Cyclohexadienone Rearrangements. Mechanistic Organic Photochemistry. XIV1, Journal of the American Chemical Society 1966 88 (1), 159-161 DOI: 10.1021/ja00953a02

Prof. Martin F. Semmelhack • Department of Chemistry, Princeton University
Frick Chemistry Laboratory – Room 190 • Princeton, NJ 08544
mfshack@princeton.edu • phone: (609) 258-5501